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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  3-DIMENSIONAL STRUCTURE IN SOLUTION OF GRISEOVIRIDIN, A GROUP-A ANTIBIOTIC


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/56357


    Title: 3-DIMENSIONAL STRUCTURE IN SOLUTION OF GRISEOVIRIDIN, A GROUP-A ANTIBIOTIC
    Authors: JAYARAMAN, G;BHASKARAN, R;YU, C;YOUNG, JJ;JUNG, LJ;LIU, WT;HO, SN;CHANG, LR
    教師: 余靖
    Date: 1994
    Publisher: Elsevier
    Relation: BIOCHIMICA ET BIOPHYSICA ACTA-GENERAL SUBJECTS, Elsevier, Volume 1201, Issue 2, NOV 11 1994, Pages 149-156
    Keywords: AMINO-ACIDS
    NMR
    REFINEMENT
    DYNAMICS
    Abstract: The solution conformation of griseoviridin, a broad spectrum antibiotic, has been determined by H-1-NMR in deuterated dimethylsulfoxide. The structural determination is based on experimental data of NOE constraints. Five structures were obtained from restrained molecular dynamics calculations, by imposing (the condition for) a minimum violation of distance constraints. These structures satisfy well the experimental restraints, with small values of NOE violation and total energies. On comparison with its crystal structure, a good agreement is noted with a backbone root-mean-square deviation value of 0.084 nm. However, a small variation between the structures is observed at the aminodecanoic acid part of the molecule.
    URI: http://www.elsevier.com/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/56357
    Appears in Collections:[化學系] 期刊論文

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