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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  1,3-and 1,2-carbo-migration of 2-vinylbicyclo[2.2-2]octenols: Facile and concise synthesis of bicyclo[4.2.2]/[3.2.2] skeleton by two/one-carbon ring expansion


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57549


    Title: 1,3-and 1,2-carbo-migration of 2-vinylbicyclo[2.2-2]octenols: Facile and concise synthesis of bicyclo[4.2.2]/[3.2.2] skeleton by two/one-carbon ring expansion
    Authors: Lu, Yan-Bin;Lee, Tsung-Ho;Liu, Wen-Cheng;Chuang, Gary Jing;Liao, Chun-Chen
    教師: 廖俊臣
    Date: 2008
    Publisher: Wiley-Blackwell
    Relation: Chemistry -Weinheim- Asian Journal,Wiley-Blackwell,Volume: 3,Issue: 8-9,Pages: 1422-1429,Published: 2008
    Keywords: OXY-COPE REARRANGEMENT
    BICYCLO<2.2.2>OCT-5-EN-2-ONE SYSTEM
    BRIDGEHEAD SUBSTITUTION
    Abstract: The synthesis of a series of bicyclo[4.2.2]octenones and bicyclo[3.2.2]heptenones by 1,3- or 1,2-migration reaction from 2-vinylbicyclo-[2.2.2]octenols is reported. These ring-expansion reactions were accomplished under basic or neutral conditions. Whether 1,3- or 1,2-migration takes place depends on endo- or exocyclic olefin displacement in the substrates
    URI: http://as.wiley.com/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57549
    Appears in Collections:[化學系] 期刊論文

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