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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  (4,7-DIMETHYL-4,7-DIAZADECANEDIAMIDE)-DIISOTHIOCYANATOCOPPER(II)


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58060


    Title: (4,7-DIMETHYL-4,7-DIAZADECANEDIAMIDE)-DIISOTHIOCYANATOCOPPER(II)
    Authors: LIN JL;LU TH;TAHIROV TH;LIU YL;CHI TY;CHUNG CS
    教師: 鐘崇燊
    Date: 1994
    Publisher: International Union of Crystallography
    Relation: Acta Crystallographica Section C Crystal Structure Communications,International Union of Crystallography,Volume: 50 Pages: 1003-1005,Part: Part 7,Published: JUL 15 1994
    Keywords: quadridentate ligand
    six-membered
    isothiocyanato groups
    Abstract: The Cu(II) ion of the title complex, [Cu(NCS)2(C10H22O2N4)], is six-coordinated in a tetragonally elongated octahedral geometry with the two amine N atoms of the quadridentate ligand and the two N atoms of the isothiocyanato groups equatorial and the two amide O atoms axial. The two N-methyl groups of the tetradentate ligand are trans to each other with respect to the equatorial plane. The complex has a cis-alpha conformation. The central five-membered ring is in a stable skew form and both of the terminal six-membered rings are in unstable twist forms. Both isothiocyanato groups are disordered.
    URI: http://www.iucr.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58060
    Appears in Collections:[化學系] 期刊論文

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