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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  [(2RS,5SR,8SR,12SR,15SR)-2,5,8,12,15-PENTAAZAHEXADECANE-KAPPA(5)N2,5,8,12,15]COPPER(II) DIPERCHLORATE


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58062


    Title: [(2RS,5SR,8SR,12SR,15SR)-2,5,8,12,15-PENTAAZAHEXADECANE-KAPPA(5)N2,5,8,12,15]COPPER(II) DIPERCHLORATE
    Authors: TAHIROV TH;LU TH;LIU YL;CHUNG CS
    教師: 鐘崇燊
    Date: 1994
    Publisher: International Union of Crystallography
    Relation: Acta Crystallographica Section C Crystal Structure Communications,International Union of Crystallography,Volume: 50 Pages: 514-516,Part: Part 4,Published: APR 15 1994
    Keywords: N-methyl groups
    stable chair form
    PENTAAZAHEXADECANE
    Abstract: The Cu(II) atom in the title complex, [Cu(C11H29N5)]-(ClO4)3, is five-coordinate and is in a distorted trigonal-bipyramidal conformation. The longer Cu(equatorial)-N bond distances compared to the Cu(axial)-N distances indicate the steric influence of the two N-methyl groups. The ligand is in its stable conformation with the three five-membered chelate rings in stable skew forms and the six-membered ring in a stable chair form.
    URI: http://journals.iucr.org/c/issues/1994/04/00/as1059/as1059.pdf
    http://www.iucr.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58062
    Appears in Collections:[化學系] 期刊論文

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