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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  [3,9-DIMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](THIOCYANATO)-COPPER(II) AND [3,6,6,9-TETRAMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](ISOTHIOCYANATO)COPPER(II)


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58068


    Title: [3,9-DIMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](THIOCYANATO)-COPPER(II) AND [3,6,6,9-TETRAMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](ISOTHIOCYANATO)COPPER(II)
    Authors: TAHIROV TH;LU TH;LUH H;LAI CY;CHUNG CS
    教師: 鐘崇燊
    Date: 1995
    Publisher: International Union of Crystallography
    Relation: Acta Crystallographica Section C Crystal Structure Communications,International Union of Crystallography,Volume: 51 Pages: 846-849,Part: Part 5,Published: MAY 15 1995
    Keywords: NICKEL(II) COMPLEX
    DEPROTONATED ANION
    DIOXIME
    Abstract: The coordination geometries about the Cu-II ions in both [3,9-dimethyl-4,8 -diaza-3,8-undecadiene-2,10-dione dioximato(1 -)](thiocyanato)copper(II), [Cu(C-11-H19N4O2)(SCN)] (1) and [3,6,6,9-tetramethyl-4,8 -diaza-3,8-undecadiene-2,10-dione dioximato(1 -)](isothiocyanato)copper(II), [CU(C13H23N4O2)(NCS)] (2), are distorted square pyramidal with the four diazadioxime N atoms in equatorial positions and the monodentate ligand axial. This monodentate axial ligand is an S-bonded thiocyanato group in complex (1) and an N-bonded isothiocyanato group in (2). The intramolecular O O hydrogen-bond lengths are 2.530(4) and 2.490(2) Angstrom in complexes (1) and (2), respectively.
    URI: http://www.iucr.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/58068
    Appears in Collections:[化學系] 期刊論文

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