National Tsing Hua University Institutional Repository:(2-methylpropane-1,2 diamine-kappa(2) N,N ')-[tris(2-aminoethyl)amine-kappa(4) N,N ',N '',N ''']-nickel(II) dipercholorate
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    NTHUR > College of Science  > Department of Chemistry > CHEM Journal / Magazine Articles  >  (2-methylpropane-1,2 diamine-kappa(2) N,N ')-[tris(2-aminoethyl)amine-kappa(4) N,N ',N '',N ''']-nickel(II) dipercholorate

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    Title: (2-methylpropane-1,2 diamine-kappa(2) N,N ')-[tris(2-aminoethyl)amine-kappa(4) N,N ',N '',N ''']-nickel(II) dipercholorate
    Authors: Lin YC;Lu TH;Li CY;Liao FL;Chung CS
    Teacher: 鐘崇燊
    Date: 2005
    Publisher: International Union of Crystallography
    Relation: Acta Crystallographica Section e,International Union of Crystallography,Volume: 61,Pages: M1398-M1400,Part: Part 7 Published: JUL 2005
    Abstract: In the title compound, [N(C4H12N2)(C6H18N4)](ClO4)(2), the Ni-II atom is coordinated in a distorted octahedron by four N atoms of the tris(2-aminoethyl)amine (tren) ligand and by two N atoms of the 2-methylpropane-1,2-diamine (2-Mepn) ligand. The primary amino group of 2-Mepn at the C-2 position occupies the position trans to the tertiary amino group of tren. The complex cations and perchlorate anions are linked via N-H center dot center dot center dot O hydrogen bonds, forming one-dimensional zigzag chains along the [101] direction.
    Appears in Collections:[Department of Chemistry] CHEM Journal / Magazine Articles

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