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    National Tsing Hua University Institutional Repository > 工學院  > 化學工程學系 > 期刊論文 >  Correlation between crystallization kinetics and microdomain morphology in block copolymer blends exhibiting confined crystallization


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/39447


    Title: Correlation between crystallization kinetics and microdomain morphology in block copolymer blends exhibiting confined crystallization
    Authors: Lee, Wenchuan;Chen, Hsin-Lung;Lin, Tsang-Lang
    教師: 陳信龍
    Date: 2002
    Publisher: John Wiley & Sons
    Relation: JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, John Wiley & Sons, Volume 40, Issue 6, MAR 15 2002, Pages 519-529
    Keywords: Block copolymers
    Polymer blends
    Crystallization
    Crosslinking
    Crystal growth
    Nucleation
    Reaction kinetics
    Homopolymerization
    Polyethylene oxides
    Polybutadienes
    X ray scattering
    Morphology
    Abstract: ©2002 Wiley - Correlation between crystallization kinetics and microdomain morphology in block copolymer blends exhibiting confined crystallization was discussed. The PB phase in a PEO-b-PB/PB blend system was crosslinked with a photocrosslinking reaction so that the melt morphology was effectively preserved on crystallization of the PEO blocks. Small angle X-ray scattering showed that microdomain structures in the melt were retained after crystallization. Homogeneous nucleation-controlled crystallization was also demonstrated in the isothermal crystallization study that showed that the crystallinity developments followed a exponential rule not encountered in the conventional spherulitic crystallization of homopolymers.
    URI: http://www.wiley.com/
    http://nthur.lib.nthu.edu.tw/handle/987654321/39447
    Appears in Collections:[化學工程學系] 期刊論文

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