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    National Tsing Hua University Institutional Repository > 工學院  > 化學工程學系 > 期刊論文 >  Conversion of poly(1,3-dihydroisothianaphthene) into polyisothianaphthene with the new dehydrogenation agent, tert-butyl hypochlorite


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/39662


    Title: Conversion of poly(1,3-dihydroisothianaphthene) into polyisothianaphthene with the new dehydrogenation agent, tert-butyl hypochlorite
    Authors: Chen, Show-An;Lee, Chin-Chang
    教師: 陳壽安
    Date: 1995
    Publisher: Elsevier
    Relation: Synthetic Metals, Elsevier, Volume 75, Issue 3, 30 December 1995, Pages 187-189
    Keywords: Conductive plastics
    Energy gap
    Dehydrogenation
    Stabilizers
    Plastic films
    Defects
    Light absorption
    Electrochromism
    Abstract: ©1995 Elsevier - The low band-gap conducting polymer, polyisothianaphthene (PITN), which is usually considered to be insoluble and cannot be processed into film, is prepared by dehydrogenation from its precursor polymer, poly(1,3-dihydroisothianaphthene) (PDHITN), in solution with the use of the new dehydrogenation agent, tert-butyl hypochlorite (tBHC), and pyridine as terminating and stabilizing agent. The PITN solution obtained is stable and a uniform PITN film can be obtained from it by casting. The resulting PITN film has less defects as reflected in its high optical absorption wavelength (λmax = 810 nm) and has good electrochromic property.
    URI: http://www.elsevier.com/
    http://nthur.lib.nthu.edu.tw/handle/987654321/39662
    Appears in Collections:[化學工程學系] 期刊論文

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