English  |  正體中文  |  简体中文  |  Items with full text/Total items : 54367/62174 (87%)
Visitors : 15086260      Online Users : 109
RC Version 6.0 © Powered By DSPACE, MIT. Enhanced by NTHU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  Detection of ClCO with time-resolved Fourier-transform infrared absorption spectroscopy


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57051


    Title: Detection of ClCO with time-resolved Fourier-transform infrared absorption spectroscopy
    Authors: Chen, SH;Chu, LK;Chen, YJ;Chen, IC;Lee, YP
    教師: 陳益佳
    Date: 2001
    Publisher: Elsevier
    Relation: CHEMICAL PHYSICS LETTERS, Elsevier, Volume 333, Issue 5, JAN 19 2001, Pages 365-370
    Keywords: KINETICS
    THERMOCHEMISTRY
    SPECTRA
    CLOO
    FCO
    Abstract: ClCO was produced as a reaction intermediate after irradiation of a flowing mixture of Cl-2/CO/Ar at 355 nm. A step-scan time-resolved Fourier-transform infrared spectrometer operated in absorption mode was employed to detect ClCO. A transient spectrum at a resolution of 0.13 cm(-1) partially reveals rotational structure with the Q-branch peaked at 1884.59 cm(-1); the transition is associated with the C-O stretching (nu (l)) mode of ClCO. Calculations with densityfunctional theory (B3LYP/aug-cc-pVTZ) predict the geometry, vibrational and rotational parameters of (ClCO)-Cl-35 and (ClCO)-Cl-37. A simulated absorption spectrum based on these parameters agrees satisfactorily with experimental observation.
    URI: http://www.elsevier.com/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57051
    Appears in Collections:[化學系] 期刊論文

    Files in This Item:

    File Description SizeFormat
    index.html0KbHTML330View/Open


    在NTHUR中所有的資料項目都受到原著作權保護,僅提供學術研究及教育使用,敬請尊重著作權人之權益。若須利用於商業或營利,請先取得著作權人授權。
    若發現本網站收錄之內容有侵害著作權人權益之情事,請權利人通知本網站管理者(smluo@lib.nthu.edu.tw),管理者將立即採取移除該內容等補救措施。

    SFX Query

    與系統管理員聯絡

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback