National Tsing Hua University Institutional Repository:Syntheses of new ruthenium clusters containing sulfur, ynyl and diynyl ligands. Crystal structures of [Ru-3(CO)(9)(mu-eta(2)-SC CSiMe3)-(mu(3)-eta(2)-C CSiMe3)], [Ru-4(CO)(12)(mu(4)-S)(mu-eta(2)-C CSiMe3)(2)] and [Ru-4(CO)(9)(mu-CO)(2)(mu(4)-S)(mu(4)-eta(2)-C(SiMe3)C(C CSiMe3)]
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    NTHUR > College of Science  > Department of Chemistry > CHEM Journal / Magazine Articles  >  Syntheses of new ruthenium clusters containing sulfur, ynyl and diynyl ligands. Crystal structures of [Ru-3(CO)(9)(mu-eta(2)-SC CSiMe3)-(mu(3)-eta(2)-C CSiMe3)], [Ru-4(CO)(12)(mu(4)-S)(mu-eta(2)-C CSiMe3)(2)] and [Ru-4(CO)(9)(mu-CO)(2)(mu(4)-S)(mu(4)-eta(2)-C(SiMe3)C(C CSiMe3)]


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57057


    Title: Syntheses of new ruthenium clusters containing sulfur, ynyl and diynyl ligands. Crystal structures of [Ru-3(CO)(9)(mu-eta(2)-SC CSiMe3)-(mu(3)-eta(2)-C CSiMe3)], [Ru-4(CO)(12)(mu(4)-S)(mu-eta(2)-C CSiMe3)(2)] and [Ru-4(CO)(9)(mu-CO)(2)(mu(4)-S)(mu(4)-eta(2)-C(SiMe3)C(C CSiMe3)]
    Authors: Alcalde MI;Carty AJ;Chi Y;Delgado E;Donnadieu B;Hernandez E;Dallmann K;Sanchez-Nieves J
    Teacher: 季昀
    Date: 2001
    Publisher: Royal Society of Chemistry
    Relation: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS,Issue: 17,Pages: 2502-2507,Published: SEP 7 2001
    Keywords: DESULFURIZATION
    1-ALKYNE-1-THIOLATO
    REACTIVITY
    CARBON
    X-RAY
    METAL-COMPLEXES
    C-S
    Abstract: Reaction of Ru-3(CO)(12) and S(C=CSiMe3)(2) in toluene gave [Ru-3(CO)(9)(mu-eta (2)-SC=CSiMe3)(mu (3)-eta (2)-C=CSiMe3)] 1. The thermolysis of 1 provokes the rupture of the S-C-sp bond of the SC=CSiMe3 ligand and C-C coupling reactions between two acetylide groups affording the clusters [Ru-3(CO)(9)(mu (3)-S)(mu (3)-eta (2)(C(SiMe3)C(C=CSiMe3)] 2, [Ru-2(CO)(6)-(mu-eta (3)-SC=CSiMe3)(mu-eta (2)-C=CSiMe3)] 3. [Ru-4(CO)(12)(mu (4)-S)(mu-eta (2)-C=CSiMe3)(2)] 4 and [Ru-4(CO)(9)(mu -CO)(2)(mu (4)-S)(mu (4)-eta (2)- C(SiMe3)C(C=CSiMe3)] 5, All compounds have been characterized by IR and NMR techniques as well as FAB(+) mass spectrometry Crystal structures of 1, 4, and 5 have been determined by X-ray diffraction methods. The pathways of the thermolysis of 1 to give 2-5 have been investigated.
    URI: http://www.rsc.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57057
    Appears in Collections:[Department of Chemistry] CHEM Journal / Magazine Articles

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