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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  Reductive alkylation of gamma-cyano-alpha, beta-unsaturated ketones: A modified Robinson annulation process to alpha,alpha-disubstituted-beta,gamma-unsaturated cyclohexanone system


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57473


    Title: Reductive alkylation of gamma-cyano-alpha, beta-unsaturated ketones: A modified Robinson annulation process to alpha,alpha-disubstituted-beta,gamma-unsaturated cyclohexanone system
    Authors: Liu HJ;Tai CL;Ly TW;Wu JD;Shia KS
    教師: 劉行讓
    Date: 2001
    Publisher: American Chemical Society
    Relation: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY,American Chemical Society,Volume: 221,Pages: U212-U212,Part: Part 2 Meeting Abstract: 679-ORGN,Published: APR 1 2001
    Keywords: ketones
    cyano compounds
    reduction
    alkylation
    Abstract: 4-Cyano-2-cyclohexenones were found to be susceptible to reductive alkylation reactions, giving the corresponding 2,2-disubstituted-3-cyclohexenone derivatives in a completely regioselective manner. This newly developed methodology has been successfully applied towards the total synthesis, in racemic form, of the marine natural product nanaimoal
    URI: http://pubs.acs.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57473
    Appears in Collections:[化學系] 期刊論文

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