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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  Carbocyclization of aromatic iodides, bicyclic alkenes, and benzynes involving a palladium-catalyzed C-H bond activation as a key step


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57947


    Title: Carbocyclization of aromatic iodides, bicyclic alkenes, and benzynes involving a palladium-catalyzed C-H bond activation as a key step
    Authors: Bhuvaneswari S;Jeganmohan M;Cheng CH
    教師: 鄭建鴻
    Date: 2006
    Publisher: American Chemical Society
    Relation: Organic Letters, American Chemical Society, Volume 8, 2006, Pages 5581-5584
    Keywords: INSERTION
    REACTIVITIES
    NORBORNADIENE
    PALLADACYCLES
    TRIPHENYLENES
    DERIVATIVES
    ARYNES
    ARYL HALIDES
    INTRAMOLECULAR ETA(2)-ARENE
    HIGHLY EFFICIENT ROUTE
    Abstract: A facile palladium-catalyzed carbocyclization reaction of aromatic iodides, bicyclic alkenes (norbornadiene, norbornene and oxabenzonorbornadiene), and benzynes to furnish various annulated 9,10-dihydrophenanthrene derivatives is described. The carbocyclization products from oxabenzonorbornadiene were further converted to polyaromatic hydrocarbons via a Lewis acid mediated deoxyaromatization reaction.
    URI: http://pubs.acs.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57947
    Appears in Collections:[化學系] 期刊論文

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