National Tsing Hua University Institutional Repository:Carbocyclization of aromatic iodides, bicyclic alkenes, and benzynes involving a palladium-catalyzed C-H bond activation as a key step
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    National Tsing Hua University Institutional Repository > 理學院 > 化學系 > 期刊論文 >  Carbocyclization of aromatic iodides, bicyclic alkenes, and benzynes involving a palladium-catalyzed C-H bond activation as a key step


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    题名: Carbocyclization of aromatic iodides, bicyclic alkenes, and benzynes involving a palladium-catalyzed C-H bond activation as a key step
    作者: Bhuvaneswari S;Jeganmohan M;Cheng CH
    教師: 鄭建鴻
    日期: 2006
    出版者: American Chemical Society
    關聯: Organic Letters, American Chemical Society, Volume 8, 2006, Pages 5581-5584
    关键词: INSERTION
    REACTIVITIES
    NORBORNADIENE
    PALLADACYCLES
    TRIPHENYLENES
    DERIVATIVES
    ARYNES
    ARYL HALIDES
    INTRAMOLECULAR ETA(2)-ARENE
    HIGHLY EFFICIENT ROUTE
    摘要: A facile palladium-catalyzed carbocyclization reaction of aromatic iodides, bicyclic alkenes (norbornadiene, norbornene and oxabenzonorbornadiene), and benzynes to furnish various annulated 9,10-dihydrophenanthrene derivatives is described. The carbocyclization products from oxabenzonorbornadiene were further converted to polyaromatic hydrocarbons via a Lewis acid mediated deoxyaromatization reaction.
    URI: http://pubs.acs.org/
    http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57947
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