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    National Tsing Hua University Institutional Repository > 歷任校長 > 劉兆玄 (1987-1993) > 期刊論文 >  Cycloaddition Reactions of Tetrafluorodisilacyclobutene with 1,3-Butadienes Mediated by Metal Carbonyls 1. 1,1,-Addition via Hydrogen Migration


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81090


    Title: Cycloaddition Reactions of Tetrafluorodisilacyclobutene with 1,3-Butadienes Mediated by Metal Carbonyls 1. 1,1,-Addition via Hydrogen Migration
    Authors: Lin, C. H.;Lee, C. Y.;Liu, C. S.
    教師: 劉兆玄
    Date: 1987
    Publisher: American Chemical Society
    Relation: ORGANOMETALLICS, American Chemical Society, Volume 6, Issue 9, SEP 1987, Pages 1861-1869
    Keywords: Silicon Organic compounds
    Silicon heterocycle
    Four membered ring
    Five membered ring
    Transition metal Complexes
    Photochemical reaction
    Mass spectrum
    NMR spectrum
    Cycloaddition
    Iron Carbonyl Complexes
    Abstract: The cycloaddition reactions of 1,1,2,2-tetrafluoro-l,2-disilacyclobutenwe ith 1,3-butadiene and its derivatives were studied. The reactions were carried out photochemically in the presence of iron pentacarbonyl. Products from the unusual metal-mediated 1.1-addition were characterized, and the reaction mechanism is discussed.
    Relation Link: http://pubs.acs.org/
    URI: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81090
    Appears in Collections:[劉兆玄 (1987-1993)] 期刊論文
    [化學系] 期刊論文

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