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    National Tsing Hua University Institutional Repository > 歷任校長 > 劉兆玄 (1987-1993) > 期刊論文 >  Cycloaddition Reactions of Tetrafluorodisilacyclobutene with 1,3-Butadienes Mediated by Metal Carbonyls. 2. Direct Cycloaddition vs. Isomerization


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81091


    Title: Cycloaddition Reactions of Tetrafluorodisilacyclobutene with 1,3-Butadienes Mediated by Metal Carbonyls. 2. Direct Cycloaddition vs. Isomerization
    Authors: Lin, C. H.;Lee, C. Y.;Liu, C. S.
    教師: 劉兆玄
    Date: 1987
    Publisher: American Chemical Society
    Relation: ORGANOMETALLICS, American Chemical Society, Volume 6, Issue 9, SEP 1987, Pages 1869-1878
    Keywords: Cycloaddition
    Isomerization
    Photochemical reaction
    Transition metal Complexes
    Silicon Organic compounds
    Silicon heterocycle
    Four membered ring
    Five membered ring
    Bicyclic compound
    Six membered ring
    NMR spectrum
    Mass spectrum
    Iron Carbonyl Complexes
    Abstract: A systematic study of the effect of substituents at both terminal carbons of 1,3-dienes is carried out in the cycloaddition reactions with 1,1,2,2-tetrafluoro-l,2-disilacyclobutemnee diated by transition-metal carbonyls. Correlation between the structures of intermediates and reaction pathways is established. Discussion is made in terms of direct cycloaddition vs. isomerization.
    Relation Link: http://pubs.acs.org/
    URI: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81091
    Appears in Collections:[劉兆玄 (1987-1993)] 期刊論文
    [化學系] 期刊論文

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