English  |  正體中文  |  简体中文  |  Items with full text/Total items : 54367/62174 (87%)
Visitors : 11236500      Online Users : 69
RC Version 6.0 © Powered By DSPACE, MIT. Enhanced by NTHU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    National Tsing Hua University Institutional Repository > 歷任校長 > 劉兆玄 (1987-1993) > 期刊論文 >  Activation of the Carbon-Carbon Bond in the Mn-mediated Cycloaddition Reaction Between Disilacyclobutene and Cyuclopeta-1,3-dienes


    Please use this identifier to cite or link to this item: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81102


    Title: Activation of the Carbon-Carbon Bond in the Mn-mediated Cycloaddition Reaction Between Disilacyclobutene and Cyuclopeta-1,3-dienes
    Authors: Chiang, H. J.;Liu, C. S.
    教師: 劉兆玄
    Date: 1992
    Publisher: Elsevier
    Relation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, Elsevier, Volume 438, Issue 1-2, OCT 13 1992, Pages C9-C12
    Keywords: PHOTOINDUCED RING EXPANSION
    CYCLO-ADDITION REACTIONS
    CARBENE COMPLEX
    SATURATED CARBON
    TRANSITION-METAL
    SIGMA-COMPLEX
    ALKYL GROUP
    REARRANGEMENT
    EXAMPLE
    TETRAFLUORODISILACYCLOBUTENE
    Abstract: The cycloaddition reaction between 1,1,2,2-tetrafluoro-1,2-disilacyclobutene and cyclohepta-1,3-diene mediated by CpMn(CO)3 under photochemical conditions generates the product SiF2((t)Bu)C=CHSiF2CH-CHCH2CH2CH2C=CH2 resulted from a C-C cleavage of the cycloheptadiene, a process involving the conversion of a sigma-bonded Mn-cyclobutane derivative to a Mn-carbene intermediate.
    Relation Link: http://www.elsevier.com/wps/find/homepage.cws_home
    URI: http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/81102
    Appears in Collections:[劉兆玄 (1987-1993)] 期刊論文
    [化學系] 期刊論文

    Files in This Item:

    File SizeFormat
    index.html0KbHTML532View/Open


    在NTHUR中所有的資料項目都受到原著作權保護,僅提供學術研究及教育使用,敬請尊重著作權人之權益。若須利用於商業或營利,請先取得著作權人授權。
    若發現本網站收錄之內容有侵害著作權人權益之情事,請權利人通知本網站管理者(smluo@lib.nthu.edu.tw),管理者將立即採取移除該內容等補救措施。

    SFX Query

    與系統管理員聯絡

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback